MATERIAL SAFETY DATA SHEET ACCORDING TO 91/155/EU Trade name: VD90.5001 / VD90.5002 / VD90.5004 / VD00.5005 / VD90.5006 / VD90.5008 / VD90.5009 / VD90.5010 / VD90.5011 / VD90.5013 MARTIN Solder Balls Issue: July 2013 Reference: MSDS Lotkugeln SnPb-e.doc 1. Identification of the substance / preparation and of the company 1.1 Identification of the substance / preparation MARTIN Solder Balls Alloy: SnPb 1.2 Company/undertaking identification MARTIN GmbH Argelsrieder Feld 1b D-82234 Wessling Phone: +49-(0)8153-932 93-0 Fax: +49-(0)8153-932 93-9 www.martin-smt.de 1.3 Emergency telephone Please contact the nearest poison emergency center. 2. Hazards identification 2.1 To people See point 11 and 15 Preparation is not classified as hazardous in the sense of directive 1999/45 EC In the event of contact with the hot product: Danger of burns The following may occur: Hazardous gases are set free when processing product Development of: Lead oxide 2.2 To the environment See point 12 3. Composition and ingredients 3.1 Alloy containing: Chemical Symbol CAS No. EINECS Content % name Tin Sn 7440-31-5 231-141-8 As per lable Lead Pb 7439-92-1 231-100-4 As per lable 4. First aid procedures 4.1 After inhalation During processing: Supply person with fresh air. Call doctor immediately. 4.2 After eye contact In the event of contact with the hot product: Wash thoroughly for several minutes using copious water. Seek medical help if necessary. 4.3 After skin contact In the event of contact with the hot product: Wash off with cold water. Do not attempt to remove hardened product. 4.4 After ingestion If with consciousness drink much water and let vomiting. Call doctor immediately have a data sheet available Martin GmbH Amtsgericht Mnchen VR-Bank Sta-Hg-Lbg Fon +49 0 8153 9329-30 D-82234 Wessling / Germany Ust.-Id.-Nr. DE 128 235 758 Konto 655 67 87 info martin-smt.de Geschftsfhrer / General Manager WEEE-Nr. DE 22908382 BIC GEN0DEF1STH www.martin-smt.de Dr. Georg Baumann IBAN DE 15700932000006556787 Dipl.-Ing Felix Frischkorn Dipl.-Ing. Gunter Krbis Page 1 of 7 MATERIAL SAFETY DATA SHEET ACCORDING TO 91/155/EU Trade name: VD90.5001 / VD90.5002 / VD90.5004 / VD00.5005 / VD90.5006 / VD90.5008 / VD90.5009 / VD90.5010 / VD90.5011 / VD90.5013 MARTIN Solder Balls Issue: July 2013 Reference: MSDS Lotkugeln SnPb-e.doc 4.5 Notes for the doctor With acute admission releasing vomiting and/or gastric lavage with approx. 2.3 % Sodium sulfate solution under additive of plentifully animal charcoal under usual safeguard clauses. Spill Sodium sulfate (1 spoon on 1 glass water) and activated charcoal, with last gastric lavage procedure Antidotum metallorum Sauter, Reducdyn or Metalcaptase or Mosatil. Of crucial importance for a rational treatment of the lead intoxication is the use of CaNa2-EDTA. Further symptomatically. No milk and alcohol. Control of the heart and cycle function. Chronically stored lead can be eliminated with a lengthy treatment with CaNa2-EDTA gradually again. Check ups after BG-principle G2 and after TRGS 505. 5. Fire fighting measures 5.1 Suitable extinguishers Adapt to the nature and extent of fire. If liquid lead is present, use dry sand. If applicable: Metal fire extinguisher 5.2 Unsuitable extinguishers If liquid lead is present, dont use water. 5.3 Severe dangers from this material, products of burning or heating In case of fire the following can develop: Fume Toxic gases Lead oxide Lead compounds 5.4 Special protective equipment Protective respirator with independent air supply According to size of fire full protection if necessary 5.5 Further information Dispose of contaminated extinction water according to official regulations 6. Accidental release measures Refer to point 13 and for personal protection refer to point 8 6.1 Personal precautions Respiratory protection, at least P2, if while handling, types of dust and smoke are developed. During strong dust and smoke development: Circulating air-independent respirator. 6.2 Environmental precautions Environmental endangerment possible with release of larger quantities of lead dust. For the water- endangering effect so far no classification took place. A penetration in underground and waters should be prevented however in any case. Inform authorities with release. 6.3 Methods of cleaning up Solutions with liquid binding material (sand, universal binder, sawdust) take up and contaminated material duly dispose of. Martin GmbH Amtsgericht Mnchen VR-Bank Sta-Hg-Lbg Fon +49 0 8153 9329-30 D-82234 Wessling / Germany Ust.-Id.-Nr. DE 128 235 758 Konto 655 67 87 info martin-smt.de Geschftsfhrer / General Manager WEEE-Nr. DE 22908382 BIC GEN0DEF1STH www.martin-smt.de Dr. Georg Baumann IBAN DE 15700932000006556787 Dipl.-Ing Felix Frischkorn Dipl.-Ing. Gunter Krbis Page 2 of 7