Article Information Sheet (AIS) This Article Information Sheet (AIS) provides relevant battery information to retailers, consumers, OEMs and others users requesting a GHS-compliant SDS. Articles, such as batteries, are exempt from GHS SDS classification criteria. The GHS criteria is not designed or intended to be used to classify the physical, health and environmental hazards of an article. Branded consumer batteries are defined as electro-technical devices. The design, safety, manufacture, and qualification of branded consumer batteries follow ANSI and IEC battery standards. This document is based on principles set forth in the following hazard communication approaches: ANSI Z-400.1, GHS, JAMP AIS, and IEC 62474. 1. Document Information Document Name Duracell Lithium HPL Cells and Batteries (primary lithium metal cells and batteries) Document ID AIS-Li HPL Issue Date 8-Dec-15 Version 2a Preparer Global Product Stewardship Last Revision 1/22/2016 Information Contact benoit.sa duracell.com 2. Company Information Name & Address Duracell Global Business Unit, 14 Research Drive, Bethel, CT USA 06801 Telephone (203) 796-4000 Website www.duracell. com Consumer Relations North America: 1-800-551-2355 (9:00 AM - 5:00 PM EST) 3. Article Information Description Duracell branded consumer lithium battery Product Category Electro-technical device Use Portable power source for electronic devices Global sub-brands (Retail) Duracell, Ultra Global sub-brands (B2B) Bulk Sizes DLCR-2, DLCR-V3, DL1/3N, DL123(DL123A DL2/3A), DL223 (DL223A), DL245, DL1604, PL123, PX28L IEC Designation CR-P2, 2CR5, CR15H270, CR11108, 2CR13252, CR17345 (IEC-60086-2 Annex D) Principles of Operation A battery powers a device by converting stored chemical energy into electrical energy. Representative Product Images 4. Article Construction Applicable Battery Industry ANSI C18.3M Part 1, ANSI C18.3M Part 2, ANSI C18.4, IEC 60086,1, IEC 60086-2, IEC Standards 60086-4 Electro-technical System Lithium Manganese Dioxide Electrode - Negative Lithium Alloy (CAS 7439-93-2) Electrode - Positive Manganese Dioxide (CAS 1313-13-9) Electrolyte Propylene Carbonate Solvent (CAS 108-32-7) Electrolyte 1,2-Dimethoxyethane Solvent (CAS 110-71-4) Materials of Construction - Can Steel (CAS 110-71-4) Declarable Substances 1-2-Dimethoxyethane (CAS 110-71-4) (IEC 62474 Criteria 1) Mercury Free Battery Yes (ANSI C18.4M <5ppm) Small Cell or Battery Sizes 1/3N, 123, 28L, CR2 fit inside a specially designed test cylinder 2.25 inches (57.1 (ANSI C18.1M Part 2 IEC 60086-5) mm) long by 1.25 inches (31.70 mm) wide. 5. Health & Safety Duracell AIS-Li HPL 1 of 6Article Information Sheet (AIS) Ingestion Required for sizes 1/3N, 123, 28L, CR2: Keep away from children. If swallowed, consult a physician immediately. Normal Conditions of Use Exposure to contents inside the sealed battery will not occur unless the battery leaks, is exposed to high temperatures, or is mechanically abused. Note to Physician Cell Ingestion: Batteries lodged in the esophagus should be removed immediately since leakage, caustic burns and perforation can occur as soon as two hours after ingestion. Irritation to the internal/external mouth areas may occur following exposure to a leaking battery. Published reports recommend removal from the esophagus should be done endoscopically (under direct visualization). Batteries beyond the esophagus need not be retrieved unless there are signs of injury to the GI tract or a large diameter battery fails to pass the pylorus. If asymptomatic, follow-up x- rays are necessary only to confirm the passage of larger batteries. Confirmation by stool inspection is preferable under most circumstances. For information on treatment, call the NATIONAL BATTERY INGESTION HOTLINE (202) 625-3333 collect, day or night (USA calls only). First Aid - If swallowed DO NOT GIVE IPECAC. Do not induce vomiting. Seek medical attention immediately. USA: CALL NATIONAL BATTERY INGESTION HOTLINE (202) 625-3333 COLLECT, DAY OR NIGHT. If mouth area irritation or burning has occurred, rinse mouth and surrounding area with tepdi water for at least 15 minutes.. First Aid - Eye Contact Flush with running water for at least 30 minutes. Seek medical attention immediately. First Aid - Skin Contact Remove contaminated clothing and flush skin with running water for at least 15 minutes. Seek medical attention if irritation persists. First Aid - Inhalation Contents of leaking battery may be irritating to respiratory passages. Move to fresh air. Seek medical attention if irritation persists. Battery Safety Standards & Testing Duracell lithium metal batteries meet the requirements of ANSI C18. 3M Part 2 and IEC 60086-4. These standards specify tests and requirements for lithium batteries to ensure safe operation under normal use and reasonably foreseeable misuse. The test regimes assess three conditions of safety. These are: 1-Intended use simulation: Partial use, vibration, thermal shock, and mechanical shock 2-Reasonably foreseeable misuse: Incorrect installation, external short-circuit, free fall (user-drop), over-discharge, and crush 3-Design consideration: Thermal abuse, mold stress Precautionary Statements CAUTION: Keep batteries away from children. If swallowed, consult a physician at once. For information on treatment, within North America call (202) 625-3333 collect. Ingestion may lead to serious injury or death. Cell can explode or leak if heated, disassembled, shorted, recharged, exposed to fire or high temperature or inserted incorrectly. Keep in original package until ready to use. Do not carry batteries loose in your pocket or purse. 6. Fire Hazard & Firefighting Fire Hazard Batteries may rupture or leak if involved in a fire. Extinguishing Media Use any extinguishing media appropriate for the surrounding area. For incipient (beginning) fires, carbon dioxide extinguishers or copious amounts of water are effective in cooling burning lithium metal batteries. If fire progresses to where lithium metal is exposed (deep red flames), use a Class D extinguisher suitable for lithium metal. Duracell AIS-Li HPL 2 of 6